Execute extension when Chrome launched

I assume this is about Windows. Here is my recommendation:

  • Get a fingerprint sensor.
  • Activate Windows Hello for the Windows account
  • Install the desktop version of Bitwarden.
  • Go to File → Settings and activate:
    • Unlock with PIN (for phone support in case the sensor has an issue)
    • Unlock with Windows Hello
    • Start To Tray Icon
    • Start automatically to login
  • Follow the steps mentioned here

Done!

So when the computer starts the user will have to follow these steps:

  • Use fingerprint sensor to log into Windows
  • Use fingerprint sensor to unlock the (hidden minimized) Bitwarden desktop app
  • Start Google Chrome (can be automated)
  • Click onto the Bitwarden extension image
  • Click Unlock with Biometrics (there unfortunately is no option to use this automatically on browser start or after clicking the icon)
  • Use fingerprint sensor to unlock the Bitwarden extension

The bold lines show processes that will be initiated automatically.

P.S.: Never underestimate a senior citizen. For details take a look here.