Can I use the Physical Authorization Key for automatic login when it is connected to my computer?

No, but there is a feature request for this that you may wish to support:

Presently, you can use a PIN code or biometrics (if your device is equipped) to unlock your vault so that you don’t have to type in your master password:
https://bitwarden.com/help/article/unlock-with-pin/
https://bitwarden.com/help/article/biometrics/

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