Setting Default Autofill With Multiple Accounts on Same Domain

My work uses the Microsoft Authentication frontend. The problem is, so do about 5 other things (XBox Live, OneDrive, personal Microsoft accounts, etc.) so I have to go up to the browser extension and select my work account each time because nothing auto-populates. That’s the login I use like 99% of the time. Is there a way to set a default login to auto-populate?