Even though I personally have set the default URI match detection method to Exact for my individual account, I would not recommend this for anybody who doesn’t deliberately make this choice for themselves based on a good understanding of the trade-offs involved.
First, the Exact setting, while being the most secure option (providing the best defense against credential theft by phishing or info-stealing scripts), is also a high-maintenance setting, requiring a significant degree of manual customization when creating new login items. For example, the account registration page, the password change page, and the login page typically have different URLs — thus, you will need to manually add at least two URLs to the login item before it will work as expected.
And since version 2025.12.0, this URL customization process has been made significantly more cumbersome, because someone at Bitwarden made the inexplicable (and completely irrational) decision to deliberately remove the “Autofill and Save” function for users who prefer Exact matching. Thus, the only way to add the required URLs is to manually copy the URL from the browser address bar, then manually edit the login item, click “Add Website”, and finally paste the URL and save the item. Repeat for the other web pages where password autofill is required.
Second, Exact matching will not work at all for some websites, if the URL for the login form is not constant. For example, the URL may include a query parameter representing some temporary token or tracking ID, and that part of the URL will change every time that you visit the login page in question. Thus, it is important to inspect each stored URL for hallmarks of variable content, then manually edit the URL string to truncate it at the start of the variable portion, and finally, customize the URI Match Detection method for that specific URL to use Starts With instead of Exact.
Third, for login forms that use an iframe to display the input fields, Bitwarden’s mismatch warning only shows the host name for the iframe source URL. Thus, one either needs to inspect the HTML source code (e.g., using DevTools) to identify the full URL for the iframe (to then manually add as an additional website for the login item), or one needs to customize the URI Match Detection method for the iframe URL to use Host instead of Exact.
Thus, using Exact as the default setting is not for the faint of heart, and I would recommend against foisting this choice on other users in your organization.